Effects of CFCs on environment
CFCs, when released from the surface of the Earth, rise slowly into the stratosphere. Once there, they are bombarded by the incoming UV light from the Sun, releasing the chlorine atoms from the parent compound, which can then react with the ozone molecules (Figure 1). Eventually the chlorine atom is removed from the atmosphere by other reactions.

Figure 1: The destruction of stratospheric ozone (6)

Chlorofluorocarbons (which are used in aerosols, refrigerants, and other industrial products) are remarkably inert and nonreactive. Indeed, it is because of these characteristics---specifically because they are nontoxic and nonflammable---that they were invented. But when they eventually rise into the stratosphere, they are decomposed by solar ultraviolet radiations into free chlorine atoms:
Chlorofluorocarbon ---> Cl,
Cl + O3 ---> ClO + O2,
ClO + O ---> Cl + O2.
The chlorine atoms are recycled in these reactions, and are then free to attack other ozone molecules. A single chlorine atom, released by the action of UV radiation on chlorofluorocarbons, is capable of destroying catalytically tens of thousands of ozone molecules during its residence in the stratosphere.
The emission of chlorofluorocarbons (CFCs) from refrigerators, air conditioners, and aerosols attributes to an increasing “hole” in the ozone layer in the atmosphere above Antarctica, coupled with growing evidence of global ozone depletion. (7)

History of CFCs as refrigerants | How CFCs affect environment? | What are the health effects of CFCs? | Ozone-depleting substance of CFCs and their phase-out dates | What are the benefits of the CFC Phase-out? | What are the substitutes for CFCs? | References